• Título:  POLY(DIPHENYLACETYLENE)S: DESIGN, SYNTHESIS AND APPLICATIONS
• Autor:  Tarrío Cordeiro, Juan José
• Universidad:  Universidad de Santiago de Compostela
• Departamento:  Escuela de Doctorado Internacional (EDIUS)
• Fecha de Lectura:  20/10/2022
• Programa de doctorado:  Programa de Doctorado en Ciencia y Tecnología Química por la Universidad de Santiago de Compostela y la Universidad de Vigo
• Dirección: 
  • QUIÑOA CABANA, EMILIO (DIRECTOR)
  • FREIRE IRIBARNE, FÉLIX (CODIRECTOR)
• Tribunal: 
  • Jiménez González, Carlos (PRESIDENTE)
  • MIGUEL ÁLVAREZ, DELIA (SECRETARIO)
  • RIBAGORDA LOBERA, MARÍA (VOCAL)
• Descriptores: 
  • ANALISIS DE MACROMOLECULAS
  • SINTESIS DE MACROMOLECULAS
  • ESTEREOQUIMICA Y ANALISIS CONFORMACIONAL
• Localización:  BIBLIOTECA XERAL USC
• 669165_1502826.pdf
• Resumen:
  This Doctoral Thesis is focused on the development of new chiral materials based on poly(diphenylacetylene)s (PDPA). PDPAs are a family of helical polymers generally described as very stable and static, where the secondary structure ¿ helical sense and/or elongation¿ cannot be modulated by external stimuli. Therefore, in this work we have explored different approaches to synthesize the first reported dynamic PDPAs, which has allowed us to create new stimuliresponsive materials. In addition, we have also focused on the elucidation of the secondary structure of those polymers to understand their structure-function relationship. These results can help the future rational design of novel smart materials with specific properties.